Structural Evolutions of Vertically Aligned Two-Dimensional MoS2 Layers Revealed by in Situ Heating Transmission Electron Microscopy
MJ Wang and JH Kim and SS Han and M Je and J Gil and C Noh and TJ Ko and KS Lee and DI Son and TS Bae and HI Ryu and KH Oh and Y Jung and H Choi and HS Chung and Y Jung, JOURNAL OF PHYSICAL CHEMISTRY C, 123, 27843-27853 (2019).
Benefiting from a large density of layer edges exposed on the surface, vertically aligned two-dimensional (2D) molybdenum disulfide (MoS2) layers have recently harvested excellent performances in the field of electrochemical catalysis and chemical sensing. With their increasing versatility for high-temperature, demanding applications, it is vital to identify their thermally driven structural and chemical stability, as well as to clarify its underlying principle. Despite various ex situ and in situ characterizations on horizontally aligned 2D MoS2 layers, the direct in situ heating of vertically aligned 2D MoS2 layers and the real-time observation of their near-atomic-scale dynamics have never been approached, leaving their thermal stability poorly understood. Moreover, the geometrical advantage of the surface-exposed vertically aligned 2D MoS2 layers is anticipated to unveil the structural dynamics of interlayer van der Waals (vdW) gaps and its correlation with thermal energy, unattainable with 2D MoS2 layers in any other geometry. Herein, we report a comprehensive in situ heating TEM study on cleanly transferred, vertically aligned 2D MoS2 layers up to 1000 degrees C. Several striking phenomena were newly observed in the course of heating: (1) formation and propagation of voids between the domains of vertical 2D MoS2 layers with distinct grain orientations starting at similar to 875 degrees C; (2) subsequent decompositions of the 2D MoS2 layers accompanying a formation of Mo nanoparticles at similar to 950 degrees C, a temperature much lower than the melting temperature of their bulk counterpart; and (3) initiation of decomposition from the surface- exposed 2D layer vertical edge sites, congruently supported by molecular dynamics (MD) simulation. These new findings will offer critical insights into better understanding the thermodynamic principle that governs the structural stability of general vdW 2D crystals as well as providing useful technological guidance for materials design and optimization in their potential high-temperature applications.
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