Effect of hygrothermal environment on traction-separation behavior of carbon fiber/epoxy interface
LH Tam and A Zhou and RX Zhang and C Wu, CONSTRUCTION AND BUILDING MATERIALS, 220, 728-738 (2019).
The strong interfacial interaction between carbon fiber and epoxy matrix plays a key role in ensuring the performance of carbon fiber reinforced polymer (CFRP). During a prolonged service-life, CFRP is inevitably exposed to the hygrothermal environment and the integrity of fiber/matrix interface is most vulnerable, but the microscopic behavior of the interface under the environmental exposure remains elusive. Here an atomistic analysis is presented on mode I and mode II traction- separation behavior between carbon fiber and epoxy matrix, which provides insights into how the surrounding water molecules at different temperature levels impact the interfacial behavior. It is found that the water molecules at the interface reduce the contact area between fiber and matrix and weaken the epoxy properties by disrupting the molecular interactions, which consequently lowers the energy barriers to interfacial separation and sliding, and the elevated temperature level further degrades the interfacial mechanical response as the epoxy becomes softened. The research findings demonstrate that the presence of water drastically deteriorates the integrity of carbon fiber/epoxy interface, and the derivation of cohesive laws based on traction separation simulation results provides a paradigm of deriving the fundamental inputs for a multiscale modeling of the interface at the continuum level by considering the environmental effect. (C) 2019 Elsevier Ltd. All rights reserved.
Return to Publications page