Hydrophobic Solvation of Gases (CO2, CH4, H-2, Noble Gases) in Clay Interlayer Nanopores
G Gadikota and B Dazas and G Rother and MC Cheshire and IC Bourg, JOURNAL OF PHYSICAL CHEMISTRY C, 121, 26539-26550 (2017).
In the past few years, experimental studies have shown that CO, is roughly 5 times more soluble in water saturated clay interlayer water than in bulk liquid water. The fundamental basis of this selectivity remains unknown, as does its relevance to other gases. Here, we use molecular dynamics (MD) simulations and gravimetric adsorption experiments to determine the solubilities of CO, CH4, H-2, and noble gases in clay interlayer water. Our results confirm that clay minerals, despite their well-known hygroscopic nature, have a significant hydrophobic character at the atomistic scale. The affinity of dissolved gases for the clay surface shows significant variations related to the size and shape of the adsorbing molecules and the structuring of interfacial water by clay surfaces. Our results indicate that dissolved gases likely do not behave as inert tracers in fine-grained sedimentary rocks such as shale and mudstone, as routinely assumed in groundwater hydrology studies. Our results have implications for the fundamental science of hydrophobic adsorption, for the use of dissolved gases as tracers of fluid migration in the subsurface, and for low-carbon energy technologies that rely on fine-grained sedimentary rocks, such as carbon capture and storage, nuclear energy, and the transition from coal to natural gas.
Return to Publications page